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81.
The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C27 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.  相似文献   
82.
A Parametric Approach for Dealing with Compositional Rounded Zeros   总被引:2,自引:0,他引:2  
In this work, a parametric approach for replacing data below the detection limit, also known as rounded zeros, in compositional data sets is proposed. Compositional rounded zeros correspond to small proportions of some whole that cannot be reliably detected by the analytical instruments under given operating conditions. This kind of zeros appear frequently in the data collection process in geosciences. They must be treated in an adequate way before some multivariate analysis can be applied. Our procedure results from a modification of the Expectation-Maximization (EM) algorithm and is based on the additive log-ratio transformation. Its coherence with the nature of compositional data and with basic operations in the simplex sample space is checked. Using real data sets, we find that this approach improves other parametric and non-parametric techniques for compositional rounded zeros.  相似文献   
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Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.  相似文献   
86.
The damage distribution in Adra town (south‐eastern Spain) during the 1993 and 1994 Adra earthquakes (5.0 magnitude), that reached a maximum intensity degree of VII (European Macroseismic Scale (EMS scale)), was concentrated mainly in the south‐east zone of the town and the most relevant damage occurred in reinforced concrete (RC) buildings with four or five storeys. In order to evaluate the influence of ground condition on RC building behaviour, geological, geomorphological and geophysical surveys were carried out, and a detailed map of ground surface structure was obtained. Short‐period microtremor observations were performed in 160 sites on a 100m × 100m dimension grid and Nakamura's method was applied in order to determine a distribution map of soil predominant periods. Shorter predominant periods (0.1–0.3 s) were found in mountainous and neighbouring zones and larger periods (greater than 0.5 s) in thicker Holocene alluvial fans. A relationship T = (0.049 ± 0.001)N, where T is the natural period of swaying motion and N is the number of storeys, has been empirically obtained by using microtremor measurements at the top of 38 RC buildings (ranging from 2 to 9 storeys). 1‐D simulation of strong motion on different soil conditions and for several typical RC buildings were computed, using the acceleration record in Adra town of the 1993 earthquake. It is noteworthy that all the aforementioned results show the influence of site effects in the degree and distribution of observed building damage. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
87.
Ground-based visible differential absorption spectrometry during twilight has been used for NO2 total column observations at the Antarctica Peninsula, Marambio Base (64S, 56W), during the austral spring of 1989 (9 September to 25 November).Results show moderate NO2 vertical column levels of 1.5 to 2.5×1015 molec cm-2 in the morning and 2 to 3×1015 molec cm-2 in the evening until middle October, highly modulated by planetary wave activity. From that date until the end of the period, a steady increase occurs which is associated with the rising of lower stratosphere temperature as the vortex weakens, reaching values of 5×1015 molec cm-2 in late November, with small a.m.-p.m. differences. NO2 is found to be positively correlated to both total ozone and 50 hPa temperature during the entire spring. However, when analyzing the departures from linear trends, a highly negative correlation has been observed from day 301 onwards.  相似文献   
88.
The study of a volcanic series from the island of Gran Canaria (Canary Islands) in which alkaline and peralkaline, saturated and undersaturated rocks coexist, is reported here. Materials with high volatile content (ignimbritic trachytes) were first emitted and the series ended with the eruption of phonolitic lavas. The average peralkalinity index in these rocks is typically about 1.0 and, therefore, peralkaline rocks coexist with non-peralkaline ones. However, a maximum in peralkalinity is found in the ignimbritic rocks of the lower part of the series. In spite of the evident acid peralkaline tendencies of these rocks, it does not seem appropriate to classify them as pantellerites or comendites. Nor are they consistent with the genetic processes proposed for rocks of similar composition and oceanic environment.The crystallization of the feldspars controls the variation trends among the different magmas but the fractionation alone does not sufficiently explain the genesis of successive fluids. Various factors seem to point to the important role which a gas-transfer process causing a geochemical stratification inside the magmatic chamber may have played.The occurrence of peralkaline silicics at Gran Canaria, which is located for away from the active Mid-Atlantic ridge, is not related to transitional basalts. These rocks are a deviation from the main undersaturated alkalic trend which characterizes the volcanism of the Canary Islands, their genesis being related to the realization of favourable local volcanic conditions.  相似文献   
89.
ABSTRACT

Water indicators and indices are useful tools to assess river basin performance, that is, to measure whether the basin operates satisfactorily under a wide range of possible future demands and hydrological conditions. Spanish regulations assess the performance of water demands by using reliability indicators (RIs), established by law in 2008. This article raises the possibility of updating RIs by comparing them with sustainability indicators (SIs). SIs are widely used for the assessment of river basin performance and several policy scenarios. We applied a water allocation model to the Guadiana River basin in Spain to compare indicators under three scenarios. The study was framed within the science of socio-hydrology, combining the physical environment of a water system with its influence on social aspects. SIs gave better results than RIs when comparing future scenarios. We also propose the introduction of a vulnerability indicator into Spanish regulations.  相似文献   
90.
The proposed existence of magnetic lineations in the Terra Cimmeria and Terra Sirenum regions of Mars was initially explained by Earth-like sea-floor spreading. Here we argue instead that these lineations could have been formed at a convergent plate margin through collision and accretion of terranes. A similar process produced banded magnetic anomalies, similar in geometry and even in size to those in Earth's North American Cordillera. Because only sparse and generally weak anomalies have been detected in the martian northern lowlands, which could constitute an analog to the terrestrial oceanic crust, it is possible that the magnetic field stopped its activity while crustal recycling was still active in Mars.  相似文献   
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